| Description | Xantphos, a ligand in the coupling reaction of Buchwald, Suzuki and others, is a metal chelating ligand that can be used to catalyze the reaction. |
| molecular weight | 578.62 |
| Molecular formula | C39H32OP2 |
| CAS | 161265-03-8 |
| Storage | Powder: -20°C for 3 years | In solvent: -80°C for 1 year | Shipping with blue ice. |
| Solubility | DMSO: < 1 mg/mL (insoluble） |
| References | 1. Song T, et al. Rhodium-Catalyzed Synthesis of Imines and Esters from Benzyl Alcohols and Nitroarenes: Change in Catalyst Reactivity Depending on the Presence or Absence of the Phosphine Ligand. J Org Chem. 2018 Apr 6;83(7):4197-4203. 2. Satishkumar S, et al. Pd-catalyzed versus uncatalyzed, PhI(OAc)(2)-mediated cyclization reactions of N(6)-([1,1'-biaryl]-2-yl)adenine nucleosides. ChemCatChem. 2017 Nov 9;9(21):4058-4069. 3. Redjdal W, et al. Convergent Synthesis of N,S-bis Glycosylquinolin-2-ones via a Pd-G3-XantPhos Precatalyst Catalysis. Molecules. 2018 Feb 26;23(3). pii: E519. 4. Keaveney ST, et al. Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides. Angew Chem Int Ed Engl. 2018 Apr 3;57(15):4073-4077. |