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Bis(4-nitrophenyl) phosphate

CAS: 645-15-8 F: C12H9N2O8P W: 340.18

Bis(4-nitrophenyl) phosphate is a catalyst for metal micelles and can catalyze the hydrolysis of (4-nitrophenyl) phospha
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Bioactivity Bis(4-nitrophenyl) phosphate is a catalyst for metal micelles and can catalyze the hydrolysis of (4-nitrophenyl) phosphate. Bis(4-nitrophenyl) phosphate is also an effective catalyst for ring-opening polymerization (ROP), which can achieve controlled polymerization of β-butyrolactone (β-BL) ring-opening and can be used to prepare diembedded polymers without quenching. segment copolymer.[1][2][3].
CAS 645-15-8
Formula C12H9N2O8P
Molar Mass 340.18
Appearance 固体
Transport Room temperature in continental US; may vary elsewhere.
Storage
Powder -20°C 3 years
4°C 2 years
In solvent -80°C 6 months
-20°C 1 month
Reference [1]. Jun L, et al. Mechanism of intramolecular nucleophilic substitution in the catalytic hydrolysis of bis (4-nitrophenyl) phosphate ester in a metallomicelle[J]. Progress in Reaction Kinetics and Mechanism, 2006, 31(4): 189-204. [2]. Xie J Q, et al. Preparation of a new metallomicelle catalyst for the hydrolysis of bis (4-nitrophenyl) phosphate[J]. Chemical Papers, 2013, 67: 365-371. [3]. Makiguchi K, et al. Bis (4‐nitrophenyl) phosphate as an efficient organocatalyst for ring‐opening polymerization of β‐butyrolactone leading to end‐functionalized and diblock polyesters[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2014, 52(14): 2032-2039.